Citric Acid Monohydrate

    • Product Name: Citric Acid Monohydrate
    • Chemical Name (IUPAC): 2-hydroxypropane-1,2,3-tricarboxylic acid monohydrate
    • CAS No.: 5949-29-1
    • Chemical Formula: C6H8O7·H2O
    • Form/Physical State: Crystalline solid
    • Factroy Site: Changsheng Street,Changle,Weifang,Shandong, China
    • Price Inquiry: sales3@liwei-chem.com
    • Manufacturer: Weifang Ensign Industry Co., Ltd.
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    Specifications

    HS Code

    140848

    Product Name Citric Acid Monohydrate
    Chemical Formula C6H8O7·H2O
    Molar Mass 210.14 g/mol
    Appearance Colorless or white crystalline powder
    Solubility In Water 146 g/100 mL (20°C)
    Melting Point 30-35°C (decomposes)
    Odor Odorless
    Ph Value 2.2 (0.1 M solution)
    Cas Number 5949-29-1
    Storage Conditions Keep tightly closed in a cool, dry, and well-ventilated place
    Density 1.542 g/cm³
    Grade Food grade / Pharmaceutical grade

    As an accredited Citric Acid Monohydrate factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.

    Packing & Storage
    Packing Citric Acid Monohydrate is packaged in a 25 kg white woven bag with a blue label, securely sealed and moisture-resistant.
    Container Loading (20′ FCL) Loaded in 20′ FCL: 25 MT per container, packed in 25kg bags, palletized or non-palletized, depending on customer preference.
    Shipping **Citric Acid Monohydrate** is shipped in sealed, moisture-proof packaging such as polyethylene-lined bags or drums, typically weighing 25 kg. Store and transport in a cool, dry, well-ventilated area, away from incompatible substances. Handle with care to prevent damage or spillage. Complies with standard chemical transportation regulations. Not classified as hazardous for shipping.
    Storage Citric Acid Monohydrate should be stored in a cool, dry, well-ventilated place, away from direct sunlight and sources of heat or ignition. Keep the container tightly closed to prevent moisture absorption and contamination. Store separately from incompatible substances such as strong bases and oxidizers. Use only approved containers, properly labeled for chemical storage, and follow local regulations for chemical handling.
    Shelf Life Citric Acid Monohydrate typically has a shelf life of 3 years when stored in a cool, dry, tightly sealed container.
    Application of Citric Acid Monohydrate

    Purity 99.5%: Citric Acid Monohydrate with 99.5% purity is used in food processing, where it ensures precise acidity regulation and flavor enhancement.

    Particle size <100 microns: Citric Acid Monohydrate with particle size under 100 microns is used in beverage formulations, where it promotes rapid dissolution and uniform distribution.

    Stability temperature up to 150°C: Citric Acid Monohydrate with stability temperature up to 150°C is used in pharmaceutical manufacturing, where it maintains chemical integrity during thermal processing.

    pH value (1% solution) 2.1: Citric Acid Monohydrate with a pH value of 2.1 (1% solution) is used in cosmetics production, where it adjusts formulation acidity to improve skin compatibility.

    Moisture content <8%: Citric Acid Monohydrate with moisture content below 8% is used in detergent applications, where it optimizes shelf stability and prevents clumping.

    Heavy metals <5 ppm: Citric Acid Monohydrate with heavy metals below 5 ppm is used in laboratory reagents, where it guarantees high purity required for analytical accuracy.

    Bulk density 0.85 g/cm³: Citric Acid Monohydrate with a bulk density of 0.85 g/cm³ is used in tablet manufacturing, where it facilitates efficient blending and compacting.

    Melting point 153°C: Citric Acid Monohydrate with a melting point of 153°C is used in confectionery production, where it allows controlled melting for texture and consistency.

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    Certification & Compliance
    More Introduction

    Citric Acid Monohydrate: From Our Factory to Your Process

    Bringing Decades of Chemical Manufacturing Experience to the Table

    Citric acid monohydrate isn’t a buzzword for us. We’ve manufactured it on site, handled it daily, and responded to years of questions from users in food, pharma, and many other sectors. Far from just being a “sour salt,” citric acid monohydrate serves as a backbone in hundreds of our customers’ operations, and we know every lot tells the story of its journey—from raw material sourcing, through controlled crystallization, right up to your application.

    What Goes into the Product

    Our citric acid monohydrate forms through fermentation of carbohydrate substrates—the same process we’ve scaled for decades. The conversion steps are watched closely since any hiccup in microbial activity throws pH, purity, or color offline. What starts as a granular feedstock ends up as a transparent crystalline powder, and the consistency matters. We run final drying and sizing checks because clumping or dusting slows down automated weighing and mixing lines. In the last five years, market demand has pushed for fewer impurities, so our specifications have adjusted: our product typically hits 99.5% minimum purity, verified in every batch using ion chromatographs and titration, and water content stays between 7.5% and 8.8%.

    Safety is baked into the workflow here for good reason. Direct human contact, dietary exposure, and the high volumes moving through plants mean there’s no room for shortcuts. Far too many recalls stem from contamination, and we recall every case over the past decade, and none came from our site. Dust control, segregated storage, and food-safe operations remain non-negotiable. We don’t believe in “food grade” as an afterthought; we manufacture to it. We keep history files on every lot and can trace raw material sources by date and shipment number.

    Physical Forms Matter; Not All Citric Acid is Built the Same

    Customers who have switched to us after years with other manufacturers usually share a common first comment—the consistency of the crystals. Citric acid monohydrate means a single water molecule per acid molecule: this matters when it comes to handling and dosage accuracy. Compare this to citric acid anhydrous, which holds no water. The water shifts the molecular weight, which in real-world terms affects how much you meter into a reactor, blend into a powdered mix, or load into a tablet press. It’s worth noting: some blenders insist on monohydrate for hygroscopic control in powdered foods or supplements, as it helps keep granules from fusing together when humidity creeps upward. Others swear by anhydrous for high-throughput applications like beverage concentrate dosing, aiming to avoid any water side effects.

    We grind and sieve our monohydrate into a range of mesh sizes. The most common particle range we support falls between 16 and 80 mesh, offering enough flexibility for everything from rapid dissolving in wet processing lines to predictable flow into solid dosage forms. Overly fine particles create dust, clog vents, and stick to chute walls—issues we’ve had to help troubleshoot for customers with less experience handling acids on their own process lines. On the coarser side, granules disperse smoothly but require longer dissolution in aqueous phases.

    Industry Use Cases Rely on Our Product’s Purity and Flow Properties

    We cannot overstate the number of sectors relying on a steady supply of citric acid monohydrate. Food producers turn to us for their acidulant needs in jams, gelatin, cheese, and beverages—where it provides tart flavor and adjusts pH, making the product shelf-stable and less prone to spoilage. We have seen entire seasons ruined by batches with haze issues or metallic off-notes, and much of that risk traces to trace ion contamination in the source product, not just the additives used elsewhere down the line. Our plant is regularly visited by customers needing independent audits for their own quality assurance, and every time—whether the concern is the lead content or cross-contamination—the product stands up to the scrutiny.

    Pharmaceutical producers come down even harder on impurities. Trying to compress a granule that doesn’t flow uniformly can destroy punch heads or cause tablets to delaminate during coating. Citric acid use isn’t limited to flavoring: it modifies pH in effervescent tablets, stabilizes vitamin C during storage, and acts as a chelating agent for certain actives that otherwise degrade or discolor. Allergen control is essential. We run multiple lines, but we dedicate tooling, bags, and rooms exclusively to citric production. No cross-over with anything that contains proteins, gluten, peanuts, tree nuts, or animal derivatives. It’s not enough to just declare allergy-free status: regular swab sampling and scheduled third-party testing keep us vigilant.

    The Technical Nuances Behind Monohydrate Choice

    Much of citric acid’s chemistry centers on the carboxyl groups and its ability to buffer pH or bind to metal ions. In monohydrate form, the crystalline structure sets melting point at about 135°C, and the presence of water helps moderate handling characteristics. Hydrated acid forms have a lower risk of dust explosions—an often-overlooked point in bulk operations, especially inside pneumatic loading or transfer systems running day and night.

    The flavor contributions differ in subtle ways: monohydrate sometimes dissolves a hair slower and diffuses into syrups or gels with slight lag, compared to anhydrous. Recipe formulations, especially powdered beverage and effervescent agents, need exact adjustments for either version. We regularly walk customers through recalculating batch sheets to account for the water of hydration: 100 grams of monohydrate holds less acid by weight compared to anhydrous. That difference plays out in taste intensity, reactivity, and even regulatory label requirements.

    Choosing between monohydrate and anhydrous comes down to a mix of technical, practical, and economic decision-making. Where the finished product will encounter temperature swings or moisture, monohydrate’s extra water content can help buffer transitions. In systems demanding rapid dissolution and precise pH control for fermentation, brewers, or pharma mixers, sometimes the anhydrous version tops the list. In our experience, seasoned formulators pay close attention to final application and adjust recipes or process parameters accordingly.

    Citric Acid Monohydrate and Clean Production Practices

    Regulatory pressure and global scrutiny on food ingredients have only ramped up in the last decade. The demand for “clean label” ingredients has forced manufacturers—ourselves included—to revisit every step from fermentation to finishing. We partner with upstream suppliers that can show farm-to-fermenter traceability of sugars and no GMOs. Auditors ask about solvents, water sources, and wastewater re-use.

    Energy use gets as much attention as chemical purity. We’ve invested in low-pressure evaporators that cut steam demand, automated pH sensors linked to process controls, and scrubbers handling trace off-gases. Every step saves not just operating budget, but narrows the line between consistent operation and production stoppages because of off-spec water or sludge.

    Communicating the story of an ingredient isn’t just about its chemical or physical stats. Increasingly, clients in North America, Europe, and Asia want assurance of sustainable manufacturing—no forced labor, ethical sourcing, and third-party certifications like FSSC 22000. Our commitment shows up in third-party audits, internal documentation, and in the continuous improvements to our plant operations.

    Long-Term Reliability and Building Trust with Partners

    Our experience tells us buyers and technical managers care less about brand glitz and more about reliability—batch after batch. Nobody enjoys the surprise of a gelatin gel failing to set or a candy batch that hardens unevenly. We’ve collaborated with R&D teams to adjust mesh size for better dispersion in drink mixes, and supported smaller plants scaling up dosing automation to cut waste in bakery lines. Every customer teaches us new problem-solving pathways, and we use their feedback to tweak process settings and quality checkpoints.

    We log every deviation, no matter how small. Missed sieve checks, humidity fluctuations, residue on filling lines—every red flag prompts a team review, sometimes leading to procedural changes. Blending operations, especially multisource mixing, have to track anti-caking agents, flow aids, and external suppliers’ raw material shifts. We’ve built traceability systems that can pinpoint mistake sources and prevent their recurrence.

    Staying Ahead with Application Support and Technical Guidance

    We invest time in onboarding new users—sometimes offering on-site troubleshooting where recipes or lines keep running into unanticipated behavior from citric acid monohydrate. A powder’s “feel” might change flow in a tablet press, or the dissolution rate in a mixing line. Our lab maintains an archive of built-in application trials, so we can suggest adjustments when results miss expectations.

    Some issues go beyond the product. One customer observed batch-to-batch inconsistency in their vitamin supplement tablet formation. Adjustments to room humidity and blending time closed the gap; the acid’s mesh size adjustment further improved weight consistency and surface finish. Such firsthand trials often show that production troubleshooting demands more than spec sheets or lab data—it demands a working knowledge of process realties.

    Challenges in a Shifting Global Landscape

    Raw material pricing remains a moving target. Sugar and molasses prices, energy tariffs, and freight costs all affect our production throughput. Experienced operators buffer inventory and hedge contracts where possible, yet black swan events—trade disputes, crop failures, pandemic-driven shutdowns—can challenge even robust supply chains. In every cyclical uptick, spending extra to stockpile key intermediates has spared clients from disruptive shortages or the need to urgently qualify substitute vendors.

    Staying on top of regulatory shifts is relentless. Governments constantly update limits on trace elements and mycotoxin screenings, prompting repeated method validation and occasional capital upgrades. Keeping product certifications up to date means extra time sunk in compliance audits, but we view this as the practical cost of long-term market access. This discipline is reflected in rigorous documentation—every step, every batch, searchable and auditable by our team or yours, on demand.

    What Makes Our Citric Acid Monohydrate Stand Out

    We view consistency from a practical viewpoint. Consistency means customers plan longer production runs without retooling or recalibrating batch weights. Our product’s clarity, colorlessness, controlled particle size distribution, and absence of off-flavors offer producers of beverages, candies, effervescent supplements, and pharma products a form of operational insurance: less downtime, fewer troubleshooting calls, and predictable results. A soda bottler doesn’t gain anything from a “unique” batch; they want their syrup acidulation to deliver identical results run after run.

    Our auditors and long-term customers alike notice the way we handle continuous improvement. We tweak fermentation parameters to boost yields, clean up the filtration line when even small spike in turbidity arises, and drop particle size dispersion that improves flow rates in high-speed packing lines. Ensuring optimal performance in automated filling or mixing equipment lies at the heart of our design choices for product grading and sizing.

    Comparing citric acid monohydrate to its cousins—like anhydrous forms or the less common tribasic salts—each fits a different niche. Monohydrate delivers reliable solubility at ambient temperatures, more storage stability under moderate humidity, and a familiar profile for those blending into dry mixes or compressing into solids. The absence of additional anti-caking or flow agents caters to formulation purists demanding fewest additives and clear label declarations.

    Where the Story Continues: Keeping Pace with Application Trends

    Shifts in the consumer packaged goods sector push more toward “natural,” “non-GMO,” and “clean-label” trends; our plant keeps up by only sourcing from verified, traceable feedstocks, and every season brings a new roster of audits. Supply partners are evaluated for chemical residues, allergen risk, and absence of any label-compromising components. The bar for product stewardship continues rising.

    Customer questions rarely stand still. Fifteen years ago, pH and purity topped the FAQ list; today, queries circle around microplastic contamination, sustainability certifications, and questions of carbon footprint or life-cycle impact. Our technical team collaborates with brand owners for direct answers—including letters of assurance, specification clarification, and documentation to power through regulatory reviews. Being a true manufacturing partner means more than shipping drums and bags: it demands insight into client goals, production quirks, and evolving market requirements.

    We see a future where ingredients like citric acid monohydrate face rising transparency demands not only on the chemical properties, but also on labor practices, local ecology, and energy consumption factors. Our approach adapts with every cycle: whether that’s re-certifying for new geographies, implementing energy conservation or zero-waste projects, or sharing production best practices with partners in collaborative R&D.

    Final Thoughts from Inside the Plant

    After decades in the business, we know the difference between moving lots and building prosperity for both our operation and our customers. Buying direct from a manufacturer means you get ownership at every level, from the correct time-stamped analysis certificate to a record of every single test run on your batch. The trust built on transparent communication and robust product performance is what makes our citric acid monohydrate a fundamental resource to so many sectors.